Display device

ABSTRACT

An organic EL display device  1  includes a flexible plastic substrate  10 , an organic EL element  4  on the plastic substrate  10 , and a sealing film  2  provided on the plastic substrate  10  to cover the organic EL element  4 . The sealing film  2  includes a first sealing layer  25  on a surface of the plastic substrate  10 , a stress relief layer  26  on a surface of the first sealing layer  25 , and a second sealing layer  27  on a surface of the stress relief layer  26 . Compressive stress of the first sealing layer  25  is lower than compressive stress of the second sealing layer  27.

TECHNICAL FIELD

The present invention relates to an organic EL display device includingan organic electroluminescence element (hereinafter referred to as an“organic EL element”).

BACKGROUND ART

In recent years, liquid crystal display devices are often used as flatpanel displays in various fields. Contrast and tinge greatly varydepending, on viewing angles. A need for a light source such as abacklight hinders reduction in power consumption. Reduction in thethickness and weight of a liquid crystal device is limited. Theseserious problems still remain. Liquid crystal devices have also seriousproblems in flexibility.

To address the problems, self-luminous organic EL display devices usingan organic EL element are expected in place of liquid crystal displaydevices in recent years. In an organic EL element, a current flowsthrough an organic EL layer between an anode and a cathode so thatorganic molecules forming the organic EL layer emit light. Beingself-luminous, organic EL display devices using such an organic ELelement are excellent in reducing the thickness, weight, and powerconsumption. In addition, organic EL display devices provide a wideviewing angle, and thus draw great attentions as flat panel displaycandidates in next generation.

Organic EL display devices using a plastic substrate draw specialattentions. A plastic substrate has higher flexibility, higher shockresistance, and lower weight than a glass substrate. A plastic substratewould provide new organic EL display devices beyond typical displaydevices using a glass substrate.

However, in general, after a certain period of drive, light-emittingcharacteristics, such as brightness and uniformity in light emission, ofan organic EL element deteriorate significantly from the initial state.The deterioration in the light-emitting characteristics attributes todeterioration of an organic layer due to moisture of outside air, whichhas entered the organic EL element, or removal of the organic layer froman electrode due to moisture.

To address the problems, providing a sealing film to reduce entry of gasgenerated by moisture is disclosed. Specifically, a disclosed functionalfilm includes a flexible plastic substrate (e.g., a film substrate), andan inorganic film (e.g., a SiO_(X) thin film) on the plastic substrate.The inorganic film is deposited on the plastic substrate at a rate of 3to 10 Å/sec, and compressive residual strain of 0.4 to 0.6% (stress of280 Mpa to 430 Mpa) is applied to the inorganic film to be formed. Thismethod increases compressive residual stress of an inorganic film,thereby manufacturing the inorganic film with increased fracture strain(see, e.g., Patent Document 1).

CITATION LIST Patent Document

[Patent Document 1] Japan Patent No. 4196440

SUMMARY OF THE INVENTION Technical Problem

However, in the method described in the Patent Document 1, an increasein the fracture strain of the SiO_(X) thin film in an amountcorresponding to the compressive residual strain reduces theadhesiveness of the SiO_(X) thin film to the plastic substrate. Thiscauses removal of the SiO_(X) film from the plastic substrate, whichresults in reduction in barrier properties against moisture.

The SiO_(X) thin film is thin and hard, and thus may crack when aflexible organic EL display device bends or curves. As a result, theSiO_(X) thin film does not reliably block the moisture of the outsideair to reduce deterioration of the organic EL element.

The present invention was made in view of the problems. It is anobjective of the present invention to provide an organic EL displaydevice, which reduces cracks at a sealing film and increases theadhesiveness of the sealing film to a plastic substrate to reducedeterioration of an organic EL element.

Solution to the Problem

In order to achieve the objective, the present invention provides afirst organic EL display device including a flexible plastic substrate,an organic EL element on the plastic substrate, and a sealing filmprovided on the plastic substrate to cover the organic EL element. Thesealing film includes a first sealing layer on a surface of the plasticsubstrate, a stress relief layer on a surface of the first sealinglayer, and a second sealing layer on a surface of the stress relieflayer. Compressive stress of the first sealing layer is lower thancompressive stress of the second sealing layer.

With this configuration, the first sealing layer has lower compressivestress than the second sealing layer. This increases the adhesiveness ofthe first sealing layer to the plastic substrate when the organic ELdisplay is bent or curved. Removal of the sealing film from the plasticsubstrate is thus reduced. As a result, barrier properties againstmoisture reduce deterioration of the organic EL element.

Since the second sealing layer, which is the outermost layer of thesealing film, has higher compressive stress than the first sealinglayer, cracks decreases at the second sealing layer when the organic ELdisplay device is bent or curved. Therefore, the second sealing, layerhas barrier properties against moisture to reduce the deterioration ofthe organic EL element.

A second organic EL display device of the present invention includes aflexible plastic substrate, an organic. EL element on the plasticsubstrate, and a sealing film provided on the plastic substrate to coverthe organic EL element. The sealing film is formed by alternatelystacking sealing layers and stress relief layers. One of the sealinglayers that is provided on a surface of the plastic substrate has lowercompressive stress than the other sealing layers.

With this configuration, the sealing layer on the surface of the plasticsubstrate has lower compressive stress than the outermost sealing layer.This increases the adhesiveness of the sealing layer on the surface ofthe plastic substrate to the plastic substrate when the organic ELdisplay device is bent or curved. Then, removal of the sealing film fromthe plastic substrate decreases. As a result, barrier properties againstmoisture reduce deterioration of the organic EL element.

Since the outermost sealing layer of the sealing film has highercompressive stress than the sealing layer on the surface of the plasticsubstrate, cracks decreases at the outermost sealing layer in bendingand curving the organic EL display device. The outermost sealing layerof the sealing film has barrier properties against moisture to reducedeterioration of the organic EL element.

Advantages of the Invention

According to the present invention, a sealing layer has barrierproperties against moisture to reduce deterioration of an organic ELelement.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross-sectional view of an organic EL display deviceaccording to a first embodiment of the present invention.

FIG. 2 is a cross-sectional view illustrating an organic EL layerforming an organic EL element included in the organic EL display deviceaccording to the first embodiment of the present invention.

FIG. 3 is a cross-sectional view illustrating a configuration of asealing film included in the organic EL display device according to thefirst embodiment of the present invention.

FIG. 4 illustrates compressive stress at the sealing film included inthe organic EL display device according to the first embodiment of thepresent invention.

FIG. 5 is a cross-sectional view illustrating a method of manufacturingthe organic EL display device according to the first embodiment of thepresent invention.

FIG. 6 is a cross-sectional view illustrating the method ofmanufacturing the organic EL display device according to the firstembodiment of the present invention.

FIG. 7 is a cross-sectional view illustrating the method ofmanufacturing the organic. EL display device according to the firstembodiment of the present invention.

FIG. 8 is a cross-sectional view illustrating the method ofmanufacturing the organic EL display device according to the firstembodiment of the present invention.

FIG. 9 is a cross-sectional view illustrating a configuration of asealing film included in an organic EL display device according to asecond embodiment of the present invention,

FIG. 10 is a cross-sectional view of an organic EL display deviceaccording to a third embodiment of the present invention.

FIG. 11 is a cross-sectional view illustrating a configuration of asealing film included in an organic EL display device according to avariation of the present invention.

FIG. 12 is a cross-sectional view illustrating a configuration of asealing film included in an organic EL display device according toanother variation of the present invention.

DESCRIPTION OF EMBODIMENTS

Embodiments of the present invention will now be described in detailwith reference to the drawings. The present invention is not limited tothe following embodiments.

First Embodiment

FIG. 1 is a cross-sectional view often organic EL display deviceaccording to a first embodiment of the present invention. FIG. 2 is across-sectional view illustrating an organic EL layer forming an organicEL element included in the organic EL display device according to thefirst embodiment of the present invention.

As shown in FIG. 1, an organic EL display device 1 includes a plasticsubstrate 10 being an element substrate, and an organic EL element 4above the plastic substrate 10.

The plastic substrate 10 is a flexible film-like substrate made of aninsulating resin material. The resin material forming the plasticsubstrate 10 may be, for example, an organic material such as polyimideresin and acrylic resin.

As shown in FIG. 1, the organic EL display device 1 includes a displayregion 15 in which the organic EL element 4 is placed. In this displayregion 15, the organic EL element 4 has a matrix structure above theplastic substrate 10. This display region 15 is formed by arrangingdisplay regions 15R emitting red light, display regions 15G emittinggreen light, and display regions 15B emitting blue light in apredetermined pattern.

As shown in FIG. 1, each organic EL element 4 includes, above theplastic substrate 10, a predetermined array (e.g., a matrix) of firstelectrodes (anodes) 13, organic EL layers 17 on the respective firstelectrodes 13, and second electrodes 14 on the respective organic ELlayers 17.

The organic EL element 4 also includes edge covers 18 to cover theperipheral edges of the first electrodes 13 and regions without thefirst electrodes 13. Each edge cover 18 is interposed between a pair ofthe pixel regions 15R, 15G, and 15B, and functions as a partitionsegmenting the pixel regions 15R, 15G, and 15B.

As shown in FIG. 1, the organic EL display device 1 includes TFTs 11 andan interlayer insulating film 21. Each TFT 11 is formed on the plasticsubstrate 10 and electrically connected to one of the first electrodes13 arranged in a predetermined array. The interlayer insulating film 21is formed on the plastic substrate 10 to cover the TFTs 11.

The first electrodes 13 function to inject holes to the respectiveorganic EL layers 17. The first electrodes 13 are preferably made of amaterial with a high work function. This is because a material with ahigh work function allows the first electrodes 13 to inject holes to theorganic EL layers 17 with higher efficiency. As shown in FIG. 1, thefirst electrodes 13 are formed on the interlayer insulating, film 21.

The material of the first electrodes 13 may include, for example, metalmaterials such as silver (Ag), aluminum (Al), vanadium (V), cobalt (Co),nickel (Ni), tungsten (W), gold (Au), calcium (Ca), titanium (Ti),yttrium (Y), sodium (Na), ruthenium (Ru), manganese (Mn), indium (In),magnesium (Mg), lithium (Li), ytterbium (Yb), and lithium fluoride(LiF). The first electrodes 13 may also be an alloy of, for example,magnesium (Mg)/copper (Cu), magnesium (Mg)/silver (Ag), sodium(Na)/potassium (K), astatine (At)/astatine dioxide (AtO₂), lithium(Li)/aluminum (Al), lithium (Li)/calcium (Ca)/aluminum (Al), or lithiumfluoride (LiF)/calcium (Ca)/aluminum (Al). The first electrodes 13 mayalso be a conductive oxide such as tin oxide (SnO), zinc oxide (ZnO),indium tin oxide (ITO), and indium zinc, oxide (IZO).

Each first electrode 13 may be a multilayer of the materials namedabove. The material with a high work function may be, for example,indium tin oxide (ITO) or indium zinc oxide (IZO).

The interlayer insulating film 21 is formed on the plastic substrate 10,and functions to flatten the surface of a film on which the TFTs 11 areprovided. Due to this interlayer insulating film 21, the firstelectrodes 13 and the organic EL layers 17 are formed flat on or abovethe interlayer insulating film 21. That is, the interlayer insulatingfilm 21 reduces an effect of steps or unevenness of the lower layers ofthe organic EL display device 1 on the shapes of the surfaces of thefirst electrodes 13, which causes ununiform light emission of theorganic EL layer 17. The interlayer insulating film 21 is made of ahighly transparent, low-cost organic resin material such as acrylicresin.

As shown in FIG. 1, the first electrodes 13 are electrically connectedto the TFTs 11 via contact holes 23 formed in the interlayer insulatingfilm 21.

Each organic EL layer 17 is formed on the surface of one of the firstelectrodes 13 segmented in a matrix. As shown in. FIG. 2, each organicEL layer 1 includes a hole injection layer 40, a hole transport layer41, a light-emitting layer 42, an electron transport layer 43, and anelectron injection layer 44. The hole transport layer 41 is formed onthe surface of the hole injection layer 40. The light-emitting layer 42is formed on the surface of the hole transport layer 41, and emits anyone of red, green, and blue light. The electron transport layer 43 isformed on the surface of the light-emitting layer 42. The electroninjection layer 44 is formed on the surface of the electron transportlayer 43. Each organic EL layer 17 is formed by sequentially stackingthe hole injection layer 40, the hole transport layer 41, thelight-emitting layer 42, the electron transport layer 43, and theelectron injection layer 44. Each organic EL layer 17 may have a smallerarea than the underlying first electrode 13 or a larger area than theunderlying first electrode 13 to cover the first electrode 13.

The hole injection layer 40 is also called an anode buffer layer, whichapproximates the energy levels between the first electrodes 13 and theorganic EL layers 17 to increase the efficiency of the first electrodes13 injecting the holes to the organic EL layers 17.

The material of the hole injection layer 40 may include, for example,triazole derivatives, oxadiazole derivatives, imidazole derivatives,polyarylalkane derivatives, pyrazoline derivatives, phenylenediaminederivatives, oxazole derivatives, styrylanthracene derivatives,fluorenone derivatives, hydrazone derivatives, and stilbene derivatives.

The hole transport layer 41 increases the efficiency in transportingholes from the first electrodes 13 to the organic EL, layers 17. Thematerial of the hole transport layer 41 may include, for example,porphyrin derivatives, aromatic tertiary amine compounds, styryl aminederivatives, polyvinylcarbazole, poly-p-phenylene vinylene, polysilane,triazole derivatives, oxadiazole derivatives, imidazole derivatives,polyarylalkane derivatives, pyrazoline derivatives, pyrazolonederivatives, phenylenediamine derivatives, arylamine derivatives,amine-substituted chalcone derivatives, oxazole derivatives,styrylanthracene derivatives, fluorenone derivatives, hydrazonederivatives, stilbene derivatives, hydrogenated amorphous silicon,hydrogenated amorphous silicon carbide, zinc sulfide, and zinc selenide.

When a voltage is applied from the first electrodes 13 and the secondelectrodes 14, holes and electrons are injected from both the electrodesto the light-emitting layer 42, in which the holes and the electrons arerecombined with each other. This light-emitting layer 42 is made of amaterial with high luminous efficiency. The material may include, forexample, metal oxinoid compounds (8-hydroxyquinoline metal complexes),naphthalene derivatives, anthracene derivatives, diphenylethylenederivatives, vinylacetone derivatives, triphenylamine derivatives,butadiene derivatives, coumarin derivatives, henzoxazole derivatives,oxadiazole derivatives oxazole derivatives, benzimidazole derivatives,thiadiazole derivatives, benzothiazole derivatives, styryl derivatives,styrylamine derivatives, bis(styryl)benzene derivatives,tris(styryl)benzene derivatives, perylene derivatives, perinonederivatives, aminopyrone derivatives, pyridine derivatives, rodaminederivatives, acridine derivatives?, phenoxazone, quinacridonederivatives, rubrene, poly-p-phenylene vinylene, and polysilane.

The electron transport layer 43 functions to efficiently move electronsto the light-emitting layer. The material of the electron transportlayer 43 may include, for example, as organic compounds, xadiazolederivatives, triazole derivatives, benzoquinone derivatives,naphthoquinone derivatives, anthraquinone derivatives,tetracyanoanthraquinodimethan derivatives, diphenoquinone derivatives,fluorenone derivatives, silole derivatives, and metal oxinoid compounds.

The electron injection layer 44 approximates the energy levels betweenthe second electrodes 14 and the organic EL layers 17 to increase theefficiency in injecting electrons from the second electrode 14 into theorganic EL layers 17, thereby reducing the drive voltage of the organicEL element 4. The electron injection layer is also called a cathodebuffer layer. The material of the electron injection layer 44 mayinclude, for example, inorganic alkaline compounds such as lithiumfluoride (LiF), magnesium fluoride (MgF₂), calcium fluoride (CaF₂),strontium fluoride (SrF₂), barium fluoride (BaF₂), Al₂O₃, and SrO.

The second electrodes 14 function to inject electrons to the organic ELlayers 17. The second electrodes 14 are preferably made of a material alow work function. This is because a material with a low work functionallows the second electrodes 14 to inject electrons to the organic ELlayers 17 with higher efficiency. As shown in FIG. 1, the secondelectrodes 14 are formed on the organic EL layers 17.

The material of the second electrodes 14 may include, for example, Oil(Ag), aluminum (Al), vanadium (V), cobalt (Co), nickel (Ni) tungsten(W), gold (Au), calcium (Ca), titanium (Ti), yttrium (Y), sodium (Na),ruthenium (Ru), manganese (Mn), indium (In), magnesium (Mg), lithium(Li), ytterbium (Yb), and lithium fluoride (LiF). The second electrodes14 may also be an alloy of magnesium (M)/copper (Cu), magnesium(Mg)/silver (Ag), sodium (Na)/potassium (K), astatine (At)/astatinedioxide (AtO₂), lithium (Li)/aluminum (Al), lithium (Li)/calcium(Ca)/aluminum (Al), or lithium fluoride (LiF)/calcium (Ca)/aluminum(Al). The second electrodes 14 may also be a conductive oxide such as atin oxide (SnO), a zinc oxide (ZnO), an indium tin oxide (ITO), and anindium zinc oxide (IZO). The second electrodes 14 may be a multilayermade of the materials named above.

The material with a low work function may be, for example, magnesium(Mg), lithium (Li), lithium fluoride (LiF), magnesium (Mg)/copper (Cu),magnesium (Mg)/silver (Ag), sodium (Na)/potassium (K), lithium(Li)/aluminum (Al), lithium (Li)/calcium (Ca)/aluminum (Al), and lithiumfluoride (LiF)/calcium (Ca)/aluminum (Al).

The edge covers 18 function to reduce short-circuit between the firstelectrodes 13 and the second electrodes 14. Thus, in one preferredembodiment, the edge covers 18 cover the entire peripheral edges of thefirst electrodes 13.

The material of the edge covers 18 may include, for example, silicondioxide (SiO₂), silicon nitride (SiN_(x), where x s a positive number)such as Si₃N₄ and silicon oxynitride (SiNO).

As shown in FIG. 1, the organic EL display device 1 also includes asealing film 2. This sealing film 2 protects the organic EL element 4from moisture. As shown in FIG. 1, the sealing film 2 is provided abovethe plastic substrate 10 to cover the organic EL element 4.

In this embodiment, as shown in FIG. 3, the sealing film 2 is providedon the surface of the plastic substrate 10. The sealing film 2 is amultilayer including a first sealing layer 25 in contact with theplastic substrate 10, a stress relief layer 26 on the surface of thefirst sealing layer 25, and a second sealing layer 27 on the stressrelief layer 26.

In this embodiment, the first sealing layer 25 has lower compressivestress than the second sealing layer 27 (i.e., the second sealing layer27 has higher compressive stress than the first sealing layer 25).

The “compressive stress” herein is the force caused when an object iscompressed from the outside to balance the inside of the object, and maybe measured by, for example, a thin film stress measurement system (TohoTechnology Inc., FLX Series).

With this configuration, when the organic EL display device 1 is bent orcurved in a predetermined direction, for example, as shown in FIG. 4,compressive stress A acts on the organic EL display device 1. However,the first sealing layer 25 on the surface of the plastic substrate 10has low compressive stress X, and thus the adhesiveness of the firstsealing layer 25 to the plastic substrate 10 increases when the organicEL display device 1 is bent or curved. Since removal of the sealing film2 from the plastic substrate 10 being bent or curved is reduced, barrierproperties against moisture improve to reduce deterioration of theorganic EL element 4.

When the organic EL display device 1 is bent or curved in thepredetermined direction as shown in FIG. 4, tensile stress B acts on theorganic EL display device 1. However, the compressive stress Y of thesecond sealing layer 27, which is the outermost layer of the sealingfilm 2, is higher than the compressive stress X of the first sealinglayer 25. The bending resistance of the second sealing layer 27 issecured when the organic EL display device 1 is bent or curved. Cracksare thus reduced at the second sealing layer 27. Therefore, the secondsealing layer 27 has barrier properties against moisture to reduce thedeterioration of the organic EL element 4.

In this embodiment, the second sealing layer 27 is provided on thestress relief layer 26. This configuration reduces the compressivestress of the second sealing layer 27 when the organic EL display device1 is bent or curved. Thus, even if the compressive stress Y of thesecond sealing layer 27 is higher than the compressive stress X of thefirst sealing layer 25, the second sealing layer 27 is not removed whenthe organic EL display device 1 is bent or curved. Cracks are thusreduced.

In this embodiment, in view of reliably increasing the bendingresistance of the second sealing layer 27, while maintaining theadhesiveness of the first sealing layer 25 to the plastic substrate 10,the difference in the compressive stress between the first and secondsealing layers 25 and 27 falls within a range from 50 MPa to 300 MPa.

The materials of the first and second sealing layers 25 and 27 are notparticularly limited, and may include inorganic materials such assilicon dioxide (SiO₂), aluminum oxide (Al₂O₃) silicon nitride (SiN_(x),where x is a positive number) such as Si₃N₄ and silicon carbonitride(SiCN).

The material of the stress relief layer 26 may include, for example,organic materials such as polysiloxime, silicon oxycarbide (SiOC),acrylate, polyurea, parylene, polyimide, and polyimide.

In one preferred embodiment, in view of allowing the organic EL element4 to have sufficient durability, the sealing film 2 has a thicknesswithin the range from 1 to 100 μm.

An exemplary method of manufacturing an organic EL display deviceaccording to this embodiment will now be described. FIGS. 5 to 8 arecross-sectional views illustrating a method of manufacturing the organicEL display device according to an embodiment of the present invention.

First, as shown in FIG. 5, the TFTs 11 for driving the organic ELelement 4 are formed at predetermined intervals on the plastic substrate10 in a size of 320×400 mm and with a thickness of 0.7 mm.

Next, as shown in FIG. 6, a photosensitive acrylic resin is applied ontothe plastic substrate 10 including the TFTs 11 by spin coating. Using anexposure mask with a predetermined exposure pattern, photosensitiveacrylic resin is exposed at a predetermined amount (e.g., 360 main²).Then, development is performed using an alkaline developer. As a result,the interlayer insulating film 21 with a thickness of for example, 2 μmis formed. After the exposure, baking is performed as post-baking undera predetermined condition at a temperature of 220° C. for 60 minutes).

At this time, the contact holes 23 with a size of, for example, 5 μm forelectrically connecting the first electrodes 13 to the TFTs 11 areformed on the interlayer insulating film 21.

As shown in FIG. 7, an ITO film is formed by sputtering, exposed tolight by photolithography and developed, and patterned by etching toform the first electrodes 13 on the interlayer insulating film 21. Atthis time, the first electrodes 13 have a thickness of, about 100 nm,for example. After the development, baking is performed as post-bakingunder a predetermined condition (e.g., at a temperature of 220° C. 120minutes). The first electrodes 13 are electrically connected to the TFTs11 via the contact holes 23 formed in the interlayer insulating film 21.

As shown in FIG. 7, a silicon dioxide film is formed at the peripheraledges of the first electrodes 13 by sputtering, exposed to light byphotolithography and developed, and patterned by etching to form theedge covers 18 to cover the entire peripheral edges of the firstelectrodes 13. At this time, the edge covers 18 have a thickness ofabout 150 nm, for example.

After that, the organic EL layers 17 including the light-emitting layer42 are formed on the first electrodes 13. Then, the second electrodes 14are formed on the organic EL layers 17. The organic EL layers 17 and thesecond electrodes 14 are formed by vapor deposition using a metal mask.

More specifically first, the plastic substrate 10 including the firstelectrodes 13 as shown in FIG. 7 is placed in a chamber of a vapordeposition system. Me inside of the chamber of the vapor depositionsystem is kept at a vacuum degree of 1×10⁻⁵ to 1×10⁻⁴ Pa by a vacuumpump. The plastic substrate 10 including the first electrodes 13 isplaced with two sides fixed to a pair of substrate receiver attached tothe inside of the chamber.

In an evaporation source, source materials (evaporants) of the holeinjection layer 40, the hole transport layer 41, the light-emittinglayer 42, the electron transport layer 43, and the electron injectionlayer 44 evaporate. Then, these layers are stacked to form the organicEL layers 17 in pixel regions as shown in FIG. 7.

Next, as shown in FIG. 7, the second electrodes 14 are formed can theorganic EL layers 17. As a result, the organic EL element 4 includingthe first electrodes 13, the organic EL layers 17, the second electrodes14, and the edge covers 18 are formed on or above the plastic substrate10.

For example, a crucible containing the evaporants are used as theevaporator source. The crucible is placed at a lower position inside thechamber, and includes a heater, which heats the crucible.

The heat of the heater allows the temperature inside the crucible toreach the evaporation temperatures of the evaporants so that theevaporants inside the crucible jump out upward as vapor inside thechamber.

A specific example method of forming the organic EL layers 17 and thesecond electrodes 14 is as follows. First, the hole injection layer 40made of m-MTDATA(4,4,4-tris(3-methylphenylphenylamino)triphenylamine) isformed with a thickness of, for example, 25 nm in common among all RGBpixels on the first electrodes 13, which is patterned on the plasticsubstrate 10, via a mask.

Then, the hole transport layer 41 made ofα-NPD(4,4-bis(N-1-naphthyl-N-phenylamino)biphenyl) is formed with athickness of, for example, 30 nm in common among all RGB pixels on thehole injection layer 40 via a mask.

Next, the light-emitting layer 42 of the red color is formed with athickness of, for example, 30 nm on the hole transport layer 41 in theassociated pixel regions via a mask. The light-emitting layer 42 of thered color is formed by mixing 30 wt % of2,6-bis((4′-methoxydiphenylamino)styryl)-1,5-dicyanonaphthalene (BSN)into di(2-naphthyl)anthracene (ADN).

After that, the light-emitting layer 42 of the green color is formedwith a thickness of, for example, 30 nm on the hole transport layer 41in the associated pixel regions via a mask. The light-emitting layer 42of the green color is formed by mixing 5 wt % of coumarin 6 into ADN.

Then, the light-emitting layer 42 of the blue color is formed with athickness of, for example, 30 nm on the hole transport layer 41 in theassociated pixel regions via a mask. The light-emitting layer 42 of theblue color is formed by mixing 2.5 wt % of4,4′-bis(2-{4-(N,N-diphenylamino)phenyl}vinyl)biphenyl(DPAVBi) into ADN.

Next, 8-hydroxyquinoline aluminum (Alq3) is formed, as the electrontransport layer 43, with a thickness of for example, 20 nm common amongall RGB pixels on the light-emitting layer 42 of all the colors via amask.

After that, lithium fluoride (LiF) is formed, as the electron injectionlayer 44, with a thickness of for example, 0.3 nm on the electrontransport layer 43 via a mask.

Then, the second electrodes 14 made of aluminum (Al) are formed with athickness of, for example, 10 nm by vacuum vapor deposition.

After that, as shown in FIG. 8, the sealing film 2 is formed on theplastic substrate 10 to cover the organic EL element 4. Morespecifically, first, inorganic materials such as silicon dioxide (SiO₂)and aluminum oxide (Al₂O₃) are stacked on the surfaces of the plasticsubstrate 10 and the organic EL element 4 by plasma CVD, vacuum vapordeposition, sputtering, atomic layer deposition (ALD) or other methodsto form the first sealing layer 25.

Next, organic materials such as acrylate, popolyurea, parylene,polyimide, and polyamide are stacked on the surface of the first sealinglayer 25 by vacuum vapor deposition to form the stress relief layer 26.

Like the first sealing layer 25 described above, inorganic materialssuch as silicon dioxide (SiO₂) and aluminum oxide (Al₂O₃) are stacked onthe surface of the stress relief layer 26 by plasma CVD, vacuum vapordeposition sputtering, atomic layer deposition (ALD), or other methodsto form the second sealing layer 27. As a result, the sealing film 2including the first sealing layer 25, the stress relief layer 26, andthe second sealing layer 27 is formed.

In the manner, the organic EL display device of this embodiment can bemanufactured.

This embodiment described above provides the following advantages.

1. In this embodiment, the sealing film 2 includes the first sealinglayer 25 on the surface of the plastic substrate 10, the stress relieflayer 26 on the surface of the first sealing layer 25, and the secondsealing layer 27 on the stress relief layer 26. The first sealing layer25 has lower compressive stress than the second sealing layer 27. Sincethe first sealing layer 25 on the surface of the plastic substrate 10has a low compressive stress, the adhesiveness of the first sealinglayer 25 to the plastic substrate 10 increases when the organic ELdisplay device 1 is bent or curved. As a result, removal of the sealingfilm 2 from the plastic substrate 10 decreases when the organic ELdisplay device 1 is bent or curved. Thus, barrier properties againstmoisture improve to reduce deterioration of the organic EL element 4.

2. The compressive stress Y of the second sealing layer 27, which is theoutermost layer of the sealing film 2, is higher than the compressivestress X of the first sealing layer 25. This configuration reducescracks at the second sealing layer 27 when the organic EL display device1 is bent or curved. Thus, the second sealing layer 27 has improvedbarrier properties against moisture to reduce the deterioration of theorganic EL element 4.

3. Since the second sealing layer 27 is formed on the stress relieflayer 26, the compressive stress of the second sealing layer 27decreases when the organic EL display device 1 is bent or curved. Thus,even if the compressive stress Y of the second sealing layer 27 ishigher than the compressive stress X of the first sealing layer 25, thesecond sealing layer 27 is not removed when the organic EL displaydevice 1 is bent or curved. Cracks are thus reduced.

4. In this embodiment, the difference in the compressive stress betweenthe first and second sealing layers 25 and 27 falls within a range from50 Mpa to 300 Mpa. With this configuration, while the first sealinglayer 25 maintains its adhesiveness to the plastic substrate 10, thesecond sealing layer 27 has reliably increased bending resistance.

5. In this embodiment, the first sealing layer 25 is formed by plasmaCVD. With this configuration, the first sealing layer 25 has higheradhesiveness to the plastic substrate 10.

6. In this embodiment, the second sealing layer 27 is formed by plasmaCVD. This further reduces cracks at the second sealing layer 27 when theorganic EL display device 1 is bent or curved.

7. In this embodiment, the stress relief layer 26 is formed by plasmaCVD. This further reduces removal of the second sealing layer 27 whenthe organic EL display device 1 is bent or curved.

Second Embodiment

A second embodiments of the present invention will now be described.FIG. 9 is a cross-sectional view illustrating a configuration of asealing film according to the second embodiment of the presentinvention. The overall configuration of the organic EL display device isthe same as that in the first embodiment, and thus detailed descriptionwill be omitted. The same reference numerals as those in the firstembodiment are used to represent equivalent elements, and the detailedexplanation thereof will be omitted.

The organic EL display device of this embodiment has the followingfeatures as shown in FIG. 9. The sealing film 2 includes a third sealinglayer 28. The sealing layers (i.e., the first, second, and third sealinglayers 25, 27, and 28) and the stress relief layers 26 are stackedalternately (three sealing layers and two the stress relief layers 26are stacked alternately in FIG. 9).

With this configuration, in this embodiment, the sealing film 2 hashigher barrier properties against moisture.

Like the first and second sealing layers 25 and 27, the third sealinglayer 28 is made of an inorganic material such as silicon dioxide(SiO₂), aluminum oxide (Al₂O₃), silicon nitride (SiN_(x), where x is apositive number) such as Si₃N₄, and silicon carbonitride (SiCN).

Like the first and second sealing layers 25 and 27, the third sealinglayer 28 is formed by stacking inorganic materials such as silicondioxide (SiO₂), aluminum oxide (Al₂O₃) on the surface of the stressrelief layer 26 by plasma CVD, vapor deposition, sputtering, atomiclayer deposition (ALD), or other methods.

As in the first embodiment, one of the sealing layers that is providedon the surface of the plastic substrate 10 (i.e., the first sealinglayer 25) has lower compressive stress than the other sealing layers(i.e., the second and third sealing layers 27 and 28) of the sealingfilm 2.

The embodiment described above provides the following advantage inaddition to the advantages 1 to 7.

8. In this embodiment, the sealing film 2 is formed by alternatelystacking the sealing layers and the stress relief layers. With thisconfiguration, the sealing film 2 has greater barrier properties againstmoisture to reliably reduce the deterioration of the organic EL element4.

Third Embodiment

A third embodiment of the present invention will now be described. FIG.10 is a cross-sectional view illustrating a configuration of a sealingfilm according to the third embodiment of the present invention. Thesame reference numerals as those in the first embodiment are used torepresent equivalent elements, and the detailed explanation thereof willbe omitted.

In this embodiment, as shown in FIG. 10, an organic EL display device 40includes a plastic substrate 20, which is a sealing substrate facing theplastic substrate 10. The organic EL element 4 formed on the plasticsubstrate 10 is interposed between the plastic substrates 10 and 20.

The organic EL display device 40 includes a sealing material 5, which isinterposed between the plastic substrates 10 and 20 and bonds theplastic substrates 10 and 20 together to encapsulate the organic ELelement 4.

The sealing material 5 is formed in a frame around the organic ELelement 4. The plastic substrates 10 and 20 are bonded together by thissealing material 5.

The plastic substrate 20 is a flexible film-like substrate made of aninsulating resin material. The resin material forming the plasticsubstrate 20 may be, for example, an organic material such as polyimideresin and acrylic resin.

The plastic substrate 20 includes a color filter 41 composed of layerscolored in red, green, or blue, and black matrixes adjacent to thecolored layers.

As shown in FIG. 10, the organic EL display device 40 includes a displayregion 15 surrounded by the sealing material 5. In this display region15, the organic EL element 4 has a matrix structure above the plasticsubstrate 10, which faces the plastic substrate 20. As described above,this display region 15 is formed by arranging display regions 15Remitting red light, display regions 15G emitting green light, anddisplay regions 15B emitting blue light in a predetermined pattern.

As shown in FIG. 10, the organic EL display device 40 also includes afiller 3 functioning as a getter (functioning to adsorb oxygen ormoisture). As shown in FIG. 10, the filler 3 is provided on the sealingfilm 2 to cover the sealing film 2.

The material of the filler 3 may include, for example, epoxy resin(e.g., thermosetting one-part epoxy resin) and silicon resin. In view ofimproving adsorption of moisture, the filler 3 contains an alkalineearth metal oxide such as calcium oxide (CaO) and barium oxide (BaO) anda desiccant such as silica gel and zeolite.

The sealing material 5 bonds the plastic substrates 10 and 20 togetherand fixes the plastic substrates 10 and 20. The material of the sealingmaterial 5 may include, for example, epoxy resin, ultraviolet (UV)curable resin such as acrylic resin, and thermosetting resin.

As shown in FIG. 10, in the organic EL display device 40, a frame region(i.e., a seal formation region) 16 for the sealing material 5 is definedaround the display region 15. As shown in FIG. 10, the sealing material5 is provided in a frame in the frame region 16 to encapsulate theorganic EL element 4, and bonds the plastic substrates 10 and 20together.

In manufacturing the organic EL display device 40 of this embodiment,first, the color filter 41 is formed on the plastic substrate 20 in asize of 320×400 mm and with a thickness of 0.7 mm.

More specifically, positive photosensitive resin is applied onto theentire plastic substrate 20 by spin coating. In the photosensitiveresin, a black pigment such as carbon fine particles is dispersed. Afterthat, the applied photosensitive resin is exposed to light via aphotomask, and then patterned by development and beating to form theblack matrix with a thickness of, for example, 2.5 μm on the plasticsubstrate 20.

Then, an acrylic photosensitive resin colored in for example, red,green, or blue is applied onto a substrate with the black matrix. Theapplied photosensitive resin is exposed to light via a photomask, andthen patterned by development to form a layer colored in the selectedcolor (e.g., a red layer R) with a thickness of, for example, 2.5 μm.For the other two colors, similar steps are repeated. Layers colored inthe other two colors (e.g., a green layer G and a blue layer B) with athickness of, for example, 2.5 μm to form the color filter 41 includingthe colored layers (the red, green, and blue layers R, G, and B).

Next, the material such as the epoxy resin is applied onto the plasticsubstrate 20 with the color filter 41 by dispending, mask printing,screen printing, or other methods to form the sealing material 5 in aframe.

Spacers (not shown are mixed into the sealing material 5 to control thedistance between the plastic substrates 10 and 20. The spacers are madeof, for example, silicon dioxide (SiO₂).

After that, the material of the filler 3 is applied to the inside thesealing material 5 on the plastic substrate 20 to be spaced apart fromthe sealing material 5 by dispending, mask printing, drop injection, orother methods. In place of the material to be applied, a sheet-likematerial may be used.

Next, in a vacuum atmosphere, the plastic substrate 20 with sealingmaterial 5 is stacked above the plastic substrate 10 with the organic ELelement 4 and the sealing film 2 (see FIG. 1) so that the material ofthe filler 3 overlaps the organic EL element 4. The surface of thesealing material 5 on the plastic substrate 20 is mounted on the surfaceof the plastic substrate 10 in the frame region 16.

Then, under a predetermined condition (e.g., under a pressure of 100 Paor lower), the inside of the sealing material 5 is kept in airtightvacuum, in a vacuum atmosphere, the plastic substrate 20 is moved towardthe plastic substrate 10 and pressed to bond the plastic substrates 10and 20 together via the sealing material 5. As a result, a bond of theplastic substrates 10 and 20 is formed.

In bonding the plastic substrates 10 and 20 together, the pressureevenly diffuses the material of the filler 3, which is formed on thesurface of the plastic substrate 20, inside sealing material 5. Thefiller 3 is provided on the sealing film 2 to cover the sealing film 2.

Next, the vacuum is purged to the atmospheric pressure (i.e., returningthe vacuum to the atmospheric pressure). Then, the plastic substrate 20is irradiated with ultraviolet (UV) light to cure the resin forming thesealing material 5. As a result, the organic EL display device 40 shownin FIG. 10 is manufactured.

The embodiment described above provides the following advantage inaddition to the advantages 1 to 7.

9. In this embodiment, the sealing material 5 configured to encapsulatethe organic EL element 4 and the filler 3 configured to cover thesealing film 2 are provided. The sealing material 5 and the filler 3block water and oxygen permeating from the outside into the sealing film2. The deterioration of the organic EL element is reliably reduced.

The embodiments may be modified as follows.

In the second embodiment, three sealing layers and two stress relieflayers are stacked alternately to form the sealing film 2. However, thenumbers of sealing layers and the stress relief layers are notparticularly limited. For example, ten sealing layers and nine stressrelief layers may he stacked alternately.

In the second embodiment, as in the third embodiment, the configurationmay include another plastic substrate, a sealing material, and a filler.The other plastic substrate faces the plastic substrate 10. The sealingmaterial is interposed between the plastic substrate 10 and the otherplastic substrate, and bonds the plastic substrate 10 and the otherplastic substrate together to encapsulate the organic EL element 4. Thefiller is provided on the sealing film 2 to cover the sealing film 2.This case also provides advantages similar to those in the thirdembodiment.

In the first embodiment, the second sealing layer 27 may cover thestress relief layer 26, as shown in FIG. 11. With this configuration,the sealing film 2 has greater barrier properties against moisture toreliably reduce the deterioration of the organic EL element 4.

In the sealing film 2 described in the second and third embodiments, theoutermost layer (i.e., the third sealing layer 28) may cover the stressrelief layer 26 as shown in FIG. 12.

In the embodiments described above, each of the organic EL layers 17 hasa multilayer structure of five layers of the hole injection layer 40,the hole transport layer 41, the light-emitting layer 42, the electrontransport layer 43, and the electron injection layer 44. The multilayerstructure is not hunted to five layers. For example, the multilayerstructure may include three layers of a hole injection and transportlayer, a light-emitting layer, and au electron injection and transportlayer.

The multilayer structure may be inverted so that the first electrodes 13function as cathodes, and the second electrodes 14 function as anodes,in this case, the multilayer structure may include, from the bottom, thefirst electrodes 13 as cathodes, the electron injection layer 44, theelectron transport layer 43, the light-emitting layer 42, the holetransport layer 41, the hole injection layer 40, and the secondelectrodes 14 as anodes. In this case, the material of the firstelectrodes 13 is replaced with the material of the second electrodes 14.

INDUSTRIAL APPLICABILITY

As described above, the present invention is suitable for an organic ELdisplay device including an organic EL element.

DESCRIPTION OF REFERENCE CHARACTERS

1 Organic EL Display Device 2 Sealing Film 3 Filler 4 Organic EL Element5 Sealing Material 10 Plastic Substrate 17 Organic EL Layer 20 PlasticSubstrate (Another Plastic Substrate) 25 First Sealing Layer 26 StressRelief Layer 27 Second Sealing Layer 28 Third Sealing Layer 40 OrganicEL Display Device

The invention claimed is:
 1. A display device comprising: a flexibleplastic substrate; an electroluminescence element disposed on theplastic substrate; and a sealing film disposed on theelectroluminescence element, wherein the sealing film includes a firstinorganic layer disposed on the electroluminescence element, an organiclayer disposed on the first inorganic layer, and a second inorganiclayer disposed on the organic layer, compressive stress of the firstinorganic layer is lower than compressive stress of the second inorganiclayer, the organic layer has another surface entirely disposed on thefirst inorganic layer, and the second inorganic layer covers an end ofthe first inorganic layer and an end of the organic layer.
 2. Thedisplay device of claim 1, wherein a difference between the compressivestress of the first inorganic layer and the compressive stress of thesecond inorganic layer falls within a range from 50 MPa to 300 MPa. 3.The display device of claim 1, wherein the second inorganic layer coversthe organic layer.
 4. The display device of claim 1, wherein the firstinorganic layer is formed by plasma CVD.
 5. The display device of claim1, wherein the second inorganic layer is formed by plasma CVD.
 6. Thedisplay device of claim 1, wherein the organic layer is formed by plasmaCVD.
 7. The display device of claim 1, further comprising: anotherplastic substrate facing the plastic substrate; a sealing materialprovided between the plastic substrate and the other plastic substrateand bonding the plastic substrate and the other plastic substratetogether to encapsulate the electroluminescence element; and a fillerprovided on the sealing film to cover the sealing film.
 8. The displaydevice of claim 1, wherein the sealing material is formed in a framearound the electroluminescence element, the plastic substrate and aflexible upper plastic substrate are bonded together, and an end of thesealing film is inside the sealing material.
 9. The display device ofclaim 8, further comprising: a filler in the sealing material, thefiller covering the sealing film and functioning as a getter.
 10. Thedisplay device of claim 1, wherein the electroluminescence elementincludes, in an order of, a first electrode, a light-emitting layer, anda second electrode from the plastic substrate.
 11. The display device ofclaim 10, wherein the first electrode includes at least any one ofsilver, aluminum, indium tin oxide, or indium zinc oxide.
 12. Thedisplay device of claim 11, wherein the first electrode is a multilayer.13. The display device of claim 10, wherein the second electrodeincludes at least any one of silver, aluminum, indium tin oxide, orindium zinc oxide.
 14. The display device of claim 13, wherein thesecond electrode is a multilayer.
 15. The display device of claim 1,wherein the electroluminescence element further includes a holeinjection layer including any one of: triazole derivatives, oxadiazolederivatives, imidazole derivatives, polyarylalkane derivatives,pyrazoline derivatives, phenylenediamine derivatives, oxazolederivatives, styrylanthracene derivatives, fluorenone derivatives,hydrazone derivatives, or stilbene derivatives.
 16. The display deviceof claim 1, wherein the electroluminescence element further includes anelectron transport layer including any one of: oxadiazole derivatives,triazole derivatives, benzoquinone derivatives, naphthoquinonederivatives, anthraquinone derivatives, tetracyanoanthraquinodimethanderivatives, diphenoquinone derivatives, fluorenone derivatives, silolederivatives, or metal oxinoid compounds.
 17. The display device of claim1, wherein the electroluminescence element further includes an electroninjection layer including any one of: lithium fluoride, magnesiumfluoride, calcium fluoride, strontium fluoride, barium fluoride, Al₂O₃,or SrO.